1.8: Experiment 7 - Precipitation (2024)

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Learning Objectives

By the end of this lab, students should be able to:

Describe precipitation reactions from the molecular perspective
Record detailed observations for a reaction.
Predict if a precipitate will form when combining two solutions.
Predict when a chemical reaction will result in the formation of a gas.
Write molecular, ionic, and net ionic equations for various reactions.
Design an experiment to determine the concentration of a known solution of an ionic species utilizing solubility rules and stoichiometry.
Calculate the concentration of a solution based on experimental (gravimetric) data.

Prior Knowledge:

3.1: Introduction to Chemical Equations
3.2: Types of Chemical Reactions
3.3: Balancing Chemical Equations
3.4: Aqueous Reactions

Aqueous solution is any solution where water is present as a solvent. Rain, vinegar, orange juice are all examples of aqueous solutions that you come across in your everyday life. In chemistry aqueous solution indicated by adding "(aq)" to the reactant formula. For example, NaCl(aq) presentas individual ions Na⁺ and Cl^- dissolved in water. You might have heard that water is the universal solvent, however, water only dissolvessubstances that are hydrophilic (from theGreek"hydros" - water and "philia" - bonding orfriendship). Compounds that do not dissolve in waterremainasolid andindicated by "(s)". For example,AgCl(s).

Supplies

Magnesium sulfate
Calcium chloride
Copper (II) Sulfate
Sodium bicarbonate (baking soda)
Vinegar (~5% acidity)
Ammonia
Scale
Clean and dry test tubes
Pipettes
Cell phone with camera
Laptop or computer with camera, speakers and microphone hooked up to internet

Solubility rules could be useful in our everyday life, but they are also extremely important in medicine. Sometimes doctors prescribe more than one solution to beadministered by theintravenous(IV)route. Mixing two solutions that form a precipitate can lead to very serious consequences. For example, magnesium sulfate is used as an electrolyte replenisher or anticonvulsant, calcium chloride isindicated in the immediate treatment of hypocalcemic tetany (abnormally low levels ofcalciumin the body that cause muscle spasm) and intravenoussodium bicarbonateis a medication primarily used to treat severe metabolic acidosis. But what will happenifyou mix them?

Procedure

Safety if you were to complete this lab in person:

Obtain and wear goggles and gloves!!!
Do non ingest any chemicals or inhale the vapors.
Clean up all spills immediately! If contact with skin rinsewith water for 15 minutes.
Before proceeding with this or any other experiment students must sign the chemical lab safety form.

For each reaction in Part A and Part Brecord your observations, molecular equation, total ionic equation and net ionic equation.Make sure to write any evidence of a chemical reaction with sufficient detail to help you distinguish between similar precipitation reactions. Don't write “became cloudy” or “white solid”. Indicate if a gel is produced or crystals form, if the solid was powdery, etc. Keep in mind that some reactions will not occur and you should write NR (for No Reaction). You will know that a reaction occurif a precipitate, a gas, or color change occurred. Heat (whether it was consumed or evolved) can also be an indicator that reaction occurred, but you may not be able to tell in these videos.

Make sure to write any evidence ofany evidence of a chemical reaction with sufficient detail to help you distinguish between similar precipitation reactions.

Week One

Reactions Worksheet

Part A. Precipitation Reaction Simulation

Group Worksheet

Before watching eachvideo predict the outcome of the reaction (formation of gas (CO₂ or H₂) or precipitate, or no reaction). Then watch the video and on your worksheet write down 1) your observations, 2) molecular equation, 3) ionic equation and 4) net ionic equation for each reaction before moving to the next video.

1.Copper(II)* sulfate and sodium phosphate

* The video says Cu₂SO₄, but the reaction shown in this video is between copper (II) sulfate and sodium phosphate.

Query \(\PageIndex{2}\)

2.Cadmium (II) chloride and sodium sulfide

Query \(\PageIndex{3}\)

3.Nickel (II) chloride and sodium carbonate

Query \(\PageIndex{4}\)

Week Two

Virtual Lab

Use the Gravimetric Analysis Virtual Lab for this assignment. Read Part I, then work in groups to complete Part II. Part III is your individual assignment and every group member will have their own unknown. You should receive an email from the TA with the unknown solution you need to use for the individual section of this assignment.

NOTE: If virtual lab says "Default Lab Setup" refresh your page

it should say: "Gravimetric Analysis of Unknown Lead Solutions"

Virtual Lab \(\PageIndex{1}\): ChemCollective Virtual Lab developed by Dave Yaron of Carnegie Mellon University, (http://www.chemcollective.org/). NOTE: if the lab loads as "Default Lab Setup" (with a bunch of acids, bases and indicators), refresh the page . You want it to load the "Gravimetric Analysis of Unknown Leas Solutions", which contains sodium chloride, potassium chromate and six unknowns.

Interactive Element

Contributors and Attributions

Robert E. Belford(University of Arkansas Little Rock; Department of Chemistry) led the creation of this page for a 5 week summer course.
Elena Lisitsynacontributed to the creation and implementation of this page, including the generation of the HP5question modules.
Mark Bailliecoordinated the modifications ofthis activity for implementation in a 15 week fall course, with the help of Elena Lisitsyna and Karie Sanford.